Thermochemical and chemical kinetic data for fluorinated hydrocarbons
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Thermochemical and chemical kinetic data for fluorinated hydrocarbons

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Published by U.S. Dept. of Commerce, Technology Administration, National Institute of Standards and Technology, For sale by the Supt. of Docs., U.S. G.P.O. in Gaithersburg, MD, Washington, DC .
Written in English


  • Fluorohydrocarbons -- Thermal properties,
  • Fire extinguishing agents -- Thermomechanical properties

Book details:

Edition Notes

StatementD.R.F. Burgess, Jr. ... [et al.]
SeriesNIST technical note -- 1412
ContributionsBurgess, D. R. F, National Institute of Standards and Technology (U.S.)
The Physical Object
Paginationvii, 174 p.
Number of Pages174
ID Numbers
Open LibraryOL14986105M

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First, he construes the term "fluorocarbon" to mean a fully fluorinated hydrocarbon (e.g., [2][6]), placing partially fluorinated hydrocarbons outside the scope of the patent claims. Curbing the Federal Circuit's enthusiasm: an argument for a rebuttable presumption against application of the doctrine of equivalents to disclosed but. Potential energy surfaces and reaction kinetics were calculated for 40 reactions involving sulfur and oxygen. This includes 11 H[subscript 2]O addition, 8 H[subscript 2]S addition, 11 hydrogen abstraction, 7 beta scission, and 3 elementary tautomerization reactions, which are potentially relevant in the combustion and desulfurization of sulfur compounds found in various fuel by: The thermodynamic and thermochemical properties of molecules, radicals, and atoms are involved one way or another in almost every computational aspect of combustion : Alexander Burcat. Fluorinated hydrocarbon synonyms, Fluorinated hydrocarbon pronunciation, Fluorinated hydrocarbon translation, English dictionary definition of Fluorinated hydrocarbon. n. An inert liquid or gaseous halocarbon compound in which fluorine replaces some or all hydrogen atoms, used as aerosol propellants, refrigerants.

Chemical kinetic modeling of high temperature hydrocarbon oxidation in combustion is reviewed. First, reaction mechanisms for specific fuels are discussed, with emphasis on the hierarchical structure of reaction mechanisms for complex by: Fluorocarbons, sometimes referred to as perfluorocarbons or PFCs, are, strictly speaking, organofluorine compounds with the formula C x F y, i.e. they contain only carbon and fluorine, though the terminology is not strictly followed. Compounds with the prefix perfluoro-are hydrocarbons, including those with heteroatoms, wherein all C-H bonds have been replaced by C-F bonds. Burgess DR Jr, Zachariah MR, Tsang W, Westmoreland PR () Thermochemical and chemical kinetic data for fluorinated hydrocarbons. Prog Energy Combust Sci – Reliable heats of formation are reported for numerous fluorinated and chlorinated methane and ethane derivatives by means of an accurate thermochemical protocol, which involves explicitly correlated coupled-cluster calculations augmented with anharmonic, scalar relativistic, and diagonal Born–Oppenheimer corrections. The theoretical results, along with additional experimental data, are Cited by: 3.

  Burgess DR Jr, Zachariah MR et al () Thermochemical and chemical kinetic data for fluorinated hydrocarbons. Prog Energy Combust Sci 21(6)– CrossRef Google Scholar Cited by: A detailed chemical kinetic mechanism has been developed to describe the oxidation of small hydrocarbon and oxygenated hydrocarbon species. In order to understand the oxidation of large hydrocarbon and oxygenated hydrocarbon fuels it is necessary to first generate a detailed understanding of the pyrolysis and oxidation kinetics of simple fuels such as hydrogen and carbon monoxide as well . 2. CHEMICAL, PHYSICAL, AND THERMOCHEMICAL PROPERTIES OF HYDROCARBONS We learned from Lecture 1 that there are three important thermochemical properties for combustion analysis. These are specific heat (or sensible enthalpy), enthalpy of formation, and entropy. In this lecture, we will learn the methods with which these properties may be estimated. ROLES OF INHIBITORS IN GLOBAL GAS-PHASE COMBUSTION KINETICS Yuko Saso National Research Institute of Fire and Disaster with the thermochemical data unchanged. The calculated Chemical Kinetic Data for Fluorinated Hydrocarbons,” Prog. Energy Combust. Sci.